Modeling of radial heat transfer in cooled fixed-bed reactors by one- and two-dimensional models: Fischer-Tropsch synthesis as a case study

• 1D and 2D pseudo-homogeneous models simulate wall-cooled FT fixed-bed reactors. • New correlation for radial heat transfer coefficient suitable for 1D models. • Method predicts stability and ignition, supporting reactor design and safety. New correlations for the overall heat transfer coefficient U th , designed for use in one-dimensional reactor models for wall-cooled tubular fixed-bed reactors, are presented. These correlations are applicable for estimating both critical conditions related to thermal runaway and reactor performance under safe operating conditions. They were derived by comparing a 1D and a 2D model, initially for Fischer-Tropsch synthesis (FTS) as a case study, and subsequently extended beyond this specific reaction system. Additionally, a novel approach is introduced for estimating critical runaway conditions without relying on a reactor model. This method is based solely on reaction kinetics, the effective thermal conductivity λ rad , and the heat transfer coefficient α wall , which accounts for heat transfer near the reactor wall.