Highly dispersed Ag nanoparticles in Ti-MOFs with partial ligand removal for catalytic conversion of CO<sub>2</sub>
A partial deligandation strategy is used to prepare Ag/NH<sub>2</sub>-MIL-125(0.5) with an extensive porous structure and abundant oxygen vacancies. This unique structural feature stabilizes highly dispersed Ag(0) nanoparticles (Ag NPs), realizing the cyclization of various propargylamines with CO<sub>2</sub> and the carboxylation of terminal alkynes at a high conversion rate under mild conditions.
Authors
- Xu Jing (ORCID: https://orcid.org/0000-0001-6877-3577)
- Chunying Duan (ORCID: https://orcid.org/0000-0003-1638-6633)
- Liu Gao
- Jinfeng Wang (ORCID: https://orcid.org/0000-0002-2568-2170)
- Qian Zhang (ORCID: https://orcid.org/0000-0003-4443-3759)
Institutions
- Dalian University of Technology (CN)
- Nanjing University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01371b
- Citations
- 1
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.70