Crystal structure and Hirshfeld surface analysis of (<i>E</i>)-2-cyano-<i>N</i>′-(3,4,5-trimethoxybenzylidene)acetohydrazide

In the title compound, C<sub>13</sub>H<sub>15</sub>N<sub>3</sub>O<sub>4</sub>, the 2-cyano-<i>N</i>'-methyl-ideneacetohydrazide moiety and the trimeth-oxy phenol ring form a dihedral angle of 13.8 (1)°. Inter-molecular N-H⋯O and C-H⋯O hydrogen bonds are observed. The inter-molecular inter-actions were qu-anti-fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter-actions contribute most to the crystal packing (38.3%).

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2025-05-02
DOI
https://doi.org/10.1107/s2056989025003913
Primary Topic
Crystal structures of chemical compounds
Type
article
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article

Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide

S. Senthilkumar, Subramani Maheswari, Sivashanmugam Selvanayagam
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
article

Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide

S. Senthilkumar, Subramani Maheswari, Sivashanmugam Selvanayagam
article en

Abstract

In the title compound, C<sub>13</sub>H<sub>15</sub>N<sub>3</sub>O<sub>4</sub>, the 2-cyano-<i>N</i>'-methyl-ideneacetohydrazide moiety and the trimeth-oxy phenol ring form a dihedral angle of 13.8 (1)°. Inter-molecular N-H⋯O and C-H⋯O hydrogen bonds are observed. The inter-molecular inter-actions were qu-anti-fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter-actions contribute most to the crystal packing (38.3%).

Acta Crystallographica Section E Crystallographic CommunicationsVol. 81(6)
Annamalai University (IN), Gastroenterology Medical Center and Hospital (IN)
Openalex Percentile: Top 92%
Crystal structures of chemical compounds
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Crystal structure and Hirshfeld surface analysis of (<i>E</i>)-2-cyano-<i>N</i>′-(3,4,5-trimethoxybenzylidene)acetohydrazide — S. Senthilkumar, Subramani Maheswari, et al. · Acta Crystallographica Section E Crystallographic Communications (2025) | TGRS Research Map | TGRS