Comparative performance assessment of multilayer insulation (MLI) systems for liquid hydrogen vessels in fire scenarios

Multilayer Insulation (MLI) systems are a mature technology for cryogenic liquid hydrogen (LH 2 ) tank thermal insulation. Recent tests evidenced that MLI materials may be damaged when exposed to fire, resulting in critical safety issues in the case of accidents. Thus, an innovative approach to the performance assessment of aluminum and polyester-based MLIs for LH 2 tanks in fire scenarios was developed. A specific model integrating the high-temperature degradation of MLIs and the thermodynamic modeling of the tank lading was coupled to specific key performance indicators. Results of the analysis applied to a vehicle-scale tank equipped with 80 MLI layers indicate that MLI degradation and consequent tank failure may occur in less than 20 min for external shell temperatures above 1160 K in the presence of full engulfment, regardless of insulation used. Conversely, degradation does not occur earlier than 3600s below 603 and 928 K for polyester and aluminum-based MLI, respectively. • Methodology for MLI performance assessment in fire scenarios involving LH 2 tanks. • KPIs and metrics introduced allow MLI performance comparison. • Aluminum-based MLI outperforms polyester-based one but both degrade in severe fires. • The failure of MLI-equipped LH 2 tanks may occur under severe fire conditions. • Controlling external shell temperature enhances tank resistance to fire.