Thermite Reactions within Liquid Gallium/Iron Oxide Supraparticles Triggered Via Induction Heating

Thermite reactions are well-known for mixtures of aluminum and iron oxide. However, other reactive metals, such as gallium, were not studied in this application, and the use of induction as an external trigger for the thermite reaction has not been established. In this work, supraparticles of gallium and iron oxide nanoparticles were synthesized to combine a low melting point with inductive heating properties. The enabled thermite-like redox reactions generate temperatures up to 900 °C within seconds in an alternating magnetic field, tunable by the material’s gallium content. Induction heating profiles are thus significantly expanded and could be applied for targeted heat-on-demand.

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Publication Details

Journal
ACS Applied Nano Materials
Published
2025-05-09
DOI
https://doi.org/10.1021/acsanm.5c01171
Citations
1
Primary Topic
Intermetallics and Advanced Alloy Properties
Type
article
Field-Weighted Citation Impact
0.71

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article

Thermite Reactions within Liquid Gallium/Iron Oxide Supraparticles Triggered Via Induction Heating

Philipp Groppe, Katrin Hurle, Karl Mandel, Michael Moritz et al.
1 citations
ACS Applied Nano Materials
Intermetallics and Advanced Alloy Properties
0.71
article

Thermite Reactions within Liquid Gallium/Iron Oxide Supraparticles Triggered Via Induction Heating

Philipp Groppe, Katrin Hurle, Karl Mandel, Michael Moritz, Christian Papp, Susanne Wintzheimer, Theodor Raczka
article en
1 citations

Abstract

Thermite reactions are well-known for mixtures of aluminum and iron oxide. However, other reactive metals, such as gallium, were not studied in this application, and the use of induction as an external trigger for the thermite reaction has not been established. In this work, supraparticles of gallium and iron oxide nanoparticles were synthesized to combine a low melting point with inductive heating properties. The enabled thermite-like redox reactions generate temperatures up to 900 °C within seconds in an alternating magnetic field, tunable by the material’s gallium content. Induction heating profiles are thus significantly expanded and could be applied for targeted heat-on-demand.

ACS Applied Nano MaterialsVol. 8(20)
Friedrich-Alexander-Universität Erlangen-Nürnberg (DE), Fraunhofer Institute for Silicate Research (DE), Freie Universität Berlin (DE)
Deutsche Forschungsgemeinschaft
Openalex Percentile: Top 33%
Intermetallics and Advanced Alloy Properties
0.71
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