Hydrochemical Characteristics and Quality Assessment of Groundwater in the Yangtze River Basin: A Comparative Study of the Hexian Area, China

The quality of shallow groundwater in agricultural areas is being increasingly threatened by nitrogen pollution. However, the complex interactions between natural and anthropogenic sources remain insufficiently studied. In this study, the water chemical characteristics and nitrogen pollution sources in key agricultural areas and counties of the Yangtze River Basin were systematically investigated. Forty-three groundwater samples were analyzed for major ions and nitrides (NH4+, NO2−, NO3−) using hydrogeochemical analysis, spatial interpolation, and positive matrix factorization (PMF) models. The shallow groundwater in the study area is weakly alkaline (pH 7.36) and is dominated by calcium ions (mean 112.67 mg/L) and bicarbonate (mean 361.95 mg/L), which reveals that the hydrogeochemical characteristics are dominated by carbonate. The total hardness has increased, and the nitrogen concentration exhibits significant spatial variability. Nitrates (NO3−) exceed safety thresholds across the entire region and are strongly correlated with Cl−. The PMF analysis identified the following four major pollution factors: Factor 1 represents a combination of anthropogenic pollution and natural processes; Factor 2 is attributed to agricultural fertilizer application and septic tank leakage; Factor 3 is sourced from the weathering of carbonates and the decomposition of organic matter in a reducing environment; and Factor 4 is due to the leakage of domestic sewage or livestock-derived wastewater. Spatial analysis revealed pollution hotspots in the vicinity of urban, agricultural, and livestock areas. This study emphasizes that human activities, such as over-fertilization and inadequate wastewater management, are the main contributors to groundwater nitrogen pollution in the study area. In addition, we compare the groundwater quality of the entire Yangtze River Basin and find that there are distinct regional variations.