Ferrocene‐Based Ozonide: [CpFeCpCH<sub>2</sub>NMe<sub>3</sub>]O<sub>3</sub>·1.47 NH<sub>3</sub>, Synthesis and Crystal Structure Analysis
The highly reactive ozonide anion could be stabilized for the first time with a ferrocene‐based cation resulting in the title compound [CpFeCpCH 2 NMe 3 ]O 3 ·1.47 NH 3 . The target compound was thoroughly characterized by X‐ray diffraction [P2 1 /c a = 1778.33(8) pm, b = 811.70(4) pm, c = 1111.71(5) pm, β = 91.715(2)°, R = 0.0325, 40301 reflections]. Additionally, infrared spectroscopy as well as quantum chemical calculations of the embedded anion were carried out to further characterize the compound and investigated the OO bond lengths and OOO bond angles of the ozonide anion.
Authors
- Martin Jansen (ORCID: https://orcid.org/0000-0003-0762-0985)
- Jonas R. Schmid (ORCID: https://orcid.org/0000-0002-9521-9317)
- Sebastian Riedel (ORCID: https://orcid.org/0000-0003-4552-5719)
- Anja Wiesner (ORCID: https://orcid.org/0000-0001-5300-2059)
- Oliver R. H. Rennefeld (ORCID: https://orcid.org/0009-0002-1027-4200)
Institutions
- Max Planck Institute for Solid State Research (DE)
- Freie Universität Berlin (DE)
Publication Details
- Journal
- Zeitschrift für anorganische und allgemeine Chemie
- Published
- 2025-05-08
- DOI
- https://doi.org/10.1002/zaac.202500066
- Citations
- 1
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Deutsche Forschungsgemeinschaft
- Freie Universität Berlin