Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands
Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P-heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.
Authors
- Ann B. Hill (ORCID: https://orcid.org/0000-0002-8962-5896)
- Ryan M. Kirk (ORCID: https://orcid.org/0000-0003-3223-5966)
Institutions
- Australian National University (AU)
- New Generation University College (ET)
- National University College (PR)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2025-05-08
- DOI
- https://doi.org/10.1002/anie.202504620
- Citations
- 4
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 3.74