Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands
Abstract Phosphinoisocyanide complexes undergo facile [3 + 2] cycloaddition reactions with activated alkynes to afford the first azaphospholylidene complexes which are rare examples of N,P ‐heterocyclic carbenes (NPHC). In addition to quantifying the donor/acceptor properties of this new class of carbene, their transmetalation reactions are also described.
Authors
- Anthony F. Hill (ORCID: https://orcid.org/0000-0003-2167-0604)
- Ryan M. Kirk
Institutions
- Australian National University (AU)
- New Generation University College (ET)
- National University College (PR)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2025-05-08
- DOI
- https://doi.org/10.1002/ange.202504620
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00