Development of Methods for the Synthesis of Bis-maleimidoaryl and Bis-allylphenol Monomers for Thermosetting Polymers

A procedure for the synthesis of bis-maleimide monomers starting from aromatic diamines has been optimized. The optimized conditions have been tested for the gram-scale synthesis with the possibility of further scaling up to a kilogram level. In addition, the conditions for the synthesis of diallylbisphenol A have been optimized with the goal of obtaining bismaleimide–bisphenol copolymers.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-03-01
DOI
https://doi.org/10.1134/s1070428024603133
Primary Topic
Epoxy Resin Curing Processes
Type
article
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article

Development of Methods for the Synthesis of Bis-maleimidoaryl and Bis-allylphenol Monomers for Thermosetting Polymers

E. S. Afanas’eva, Oleg S. Morozov, Alexey Yu. Fedorov, Vasilii F. Otvagin et al.
Russian Journal of Organic Chemistry
Epoxy Resin Curing Processes
article

Development of Methods for the Synthesis of Bis-maleimidoaryl and Bis-allylphenol Monomers for Thermosetting Polymers

E. S. Afanas’eva, Oleg S. Morozov, Alexey Yu. Fedorov, Vasilii F. Otvagin, Ekaterina S. Kudriashova, А. В. Бабкин, K. A. Romanov
article en

Abstract

A procedure for the synthesis of bis-maleimide monomers starting from aromatic diamines has been optimized. The optimized conditions have been tested for the gram-scale synthesis with the possibility of further scaling up to a kilogram level. In addition, the conditions for the synthesis of diallylbisphenol A have been optimized with the goal of obtaining bismaleimide–bisphenol copolymers.

Russian Journal of Organic ChemistryVol. 61(3)
Lomonosov Moscow State University (RU), N. I. Lobachevsky State University of Nizhny Novgorod (RU), Yaroslav-the-Wise Novgorod State University (RU)
Openalex Percentile: Top 91%
Epoxy Resin Curing Processes
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