Synthesis of Macrocyclic Tetraoxadithiaspiroalkanes in the Presence of Lanthanide Catalysts

An efficient method has been developed for the synthesis of macrocyclic tetraoxadithiaspiroalkanes by the cyclocondensation of alkane-α,ω-dithiols (butane-1,4-dithiol, pentane-1,5-dithiol, and hexane-1,6-dithiol) with 1,1-dihydroperoxycycloalkanes and formaldehyde in the presence of lanthanide catalysts.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-03-01
DOI
https://doi.org/10.1134/s1070428024603765
Primary Topic
Synthesis and Reactivity of Sulfur-Containing Compounds
Type
article
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article

Synthesis of Macrocyclic Tetraoxadithiaspiroalkanes in the Presence of Lanthanide Catalysts

Nataliya N. Makhmudiyarova, Usein Memetovich Dzhemilev, I. R. Ishmukhametova
Russian Journal of Organic Chemistry
Synthesis and Reactivity of Sulfur-Containing Compounds
article

Synthesis of Macrocyclic Tetraoxadithiaspiroalkanes in the Presence of Lanthanide Catalysts

Nataliya N. Makhmudiyarova, Usein Memetovich Dzhemilev, I. R. Ishmukhametova
article en

Abstract

An efficient method has been developed for the synthesis of macrocyclic tetraoxadithiaspiroalkanes by the cyclocondensation of alkane-α,ω-dithiols (butane-1,4-dithiol, pentane-1,5-dithiol, and hexane-1,6-dithiol) with 1,1-dihydroperoxycycloalkanes and formaldehyde in the presence of lanthanide catalysts.

Russian Journal of Organic ChemistryVol. 61(3)
N.D. Zelinsky Institute of Organic Chemistry (RU), Ufa Institute of Chemistry (RU)
Openalex Percentile: Top 93%
Synthesis and Reactivity of Sulfur-Containing Compounds
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