Study on Temporal and Spatial Distribution Characteristics of Biogenic Pollutant Fluxes in Ten Main Rivers Discharging into the Sea in Eastern China

Rapid economic development, accelerated urbanization, and agricultural modernization in eastern China have exacerbated pollution in rivers discharging into the sea, challenging regional ecological security and water resource sustainability. This study investigates ten main rivers in eastern China using monthly water quality and hydrological data from 2021 to 2023. Pollutant fluxes for permanganate index (CODMn), ammonia nitrogen (AN), total phosphorus (TP), and total nitrogen (TN) were calculated, and their temporal and spatial variations were analyzed using descriptive statistics, two-way analysis of variance (ANOVA), and principal component analysis (PCA). Results show significant spatial heterogeneity, with the Yangtze (YAR) and Pearl Rivers (PER) exhibiting the highest fluxes due to high basin runoff and intense human activities. Seasonal variations significantly affect CODMn, TP, and TN fluxes, with summer runoff and agricultural activities enhancing pollutant transport. Moreover, flood periods markedly increase pollutant fluxes compared to non-flood periods. PCA further reveals that the pollutant flux patterns of YAR and PER are clearly distinct from those of the other rivers, indicating the joint influence of geographic conditions and anthropogenic activities. This study provides quantitative evidence for regional water environment management and offers crucial guidance for developing sustainable, differentiated pollution control strategies.