Lanthanide Heterometallic MOFs with 5-Iodosophthalate Linkers: Tuning of Luminescent Properties by Varying of Metal Composition
Coordination polymers [Gd2(5-iip)3(DMF)4]·0.4DMF (1) and [Dy2(5-iip)3DMF2]·0.33DMF (2) (5-iip2−—5-iodoisophthalate) feature two different structural types, as follows from X-ray diffractometry data. We prepared and characterized an extended series of corresponding heterometallic complexes of the composition [GdxDy2−x(5-iip)3DMF2]·0.33DMF and [EuxDy2−x(5-iip)3DMF2]·0.33DMF, where x = 0.2, 0.4…1.8, and examined the changes of their luminescent properties induced by variations of metal composition, finding the promising white emission sources with high light purity.
Authors
- E. A. Maximovskiy (ORCID: https://orcid.org/0000-0002-1555-2719)
- Vladimir P. Fedin (ORCID: https://orcid.org/0000-0001-8922-0066)
- А. S. Zaguzin (ORCID: https://orcid.org/0000-0001-7269-1750)
- Sergey A. Adonin (ORCID: https://orcid.org/0000-0002-9889-5273)
- Tatiana Ya. Guselnikova (ORCID: https://orcid.org/0000-0003-3584-9074)
- Nikita A. Korobeynikov (ORCID: https://orcid.org/0000-0003-3399-5975)
- Mikhail A. Bondarenko
- М. И. Рахманова
- R. V. Red’kin
- E. A. Pilyukova
Institutions
- Novosibirsk State University (RU)
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
- Nikolaev Institute of Inorganic Chemistry (RU)
Publication Details
- Journal
- Inorganics
- Published
- 2025-05-07
- DOI
- https://doi.org/10.3390/inorganics13050154
- Citations
- 1
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.54
Funders
- Russian Science Foundation