<scp>l</scp>-Tyrosine-Derived Nitrogen-Doped Carbon Dots Synthesized via a Hydrothermal Approach for Corrosion Mitigation of Mild Steel in 15% Hydrochloric Acid Solution

l-Tyrosine-based eco-friendly nitrogen-doped carbon dots have been synthesized using citric acid and isoniazid as precursors along with l-tyrosine via a facile one-pot hydrothermal approach for the corrosion mitigation of mild steel (MS) in HCl solution (15%). The authenticity of the synthesized carbon dots has been established using various spectroscopic techniques such as X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), and Fourier transform infrared (FT-IR) spectroscopy. The inhibition behavior was studied using gravimetric analysis, electrochemical measurements, and surface analysis. The potentiodynamic polarization revealed that the N-doped carbon dots act as a mixed-type corrosion inhibitor; that is, it can act as both a cathodic as well as an anodic inhibitor, with the corrosion efficiency of 99.3% at the concentration of 150 ppm. N-CDs protect the metal surface by forming a layer that is particularly physisorbed as confirmed by Δ<i>G</i><sub>abs</sub> values.

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Publication Details

Journal
Langmuir
Published
2025-05-05
DOI
https://doi.org/10.1021/acs.langmuir.5c00885
Citations
21
Primary Topic
Carbon and Quantum Dots Applications
Type
article
Field-Weighted Citation Impact
10.87
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article

l-Tyrosine-Derived Nitrogen-Doped Carbon Dots Synthesized via a Hydrothermal Approach for Corrosion Mitigation of Mild Steel in 15% Hydrochloric Acid Solution

Tarun Kanti Sarkar, Navjot Sandhu, Vandana Saraswat, Sonia Kumari
21 citations
Langmuir
Carbon and Quantum Dots Applications
10.87
article

l-Tyrosine-Derived Nitrogen-Doped Carbon Dots Synthesized via a Hydrothermal Approach for Corrosion Mitigation of Mild Steel in 15% Hydrochloric Acid Solution

Tarun Kanti Sarkar, Navjot Sandhu, Vandana Saraswat, Sonia Kumari
article en
21 citations

Abstract

l-Tyrosine-based eco-friendly nitrogen-doped carbon dots have been synthesized using citric acid and isoniazid as precursors along with l-tyrosine via a facile one-pot hydrothermal approach for the corrosion mitigation of mild steel (MS) in HCl solution (15%). The authenticity of the synthesized carbon dots has been established using various spectroscopic techniques such as X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), and Fourier transform infrared (FT-IR) spectroscopy. The inhibition behavior was studied using gravimetric analysis, electrochemical measurements, and surface analysis. The potentiodynamic polarization revealed that the N-doped carbon dots act as a mixed-type corrosion inhibitor; that is, it can act as both a cathodic as well as an anodic inhibitor, with the corrosion efficiency of 99.3% at the concentration of 150 ppm. N-CDs protect the metal surface by forming a layer that is particularly physisorbed as confirmed by Δ<i>G</i><sub>abs</sub> values.

LangmuirVol. 41(19)
Chandigarh University (IN), Galgotias University (IN), IFTM University (IN), Division of Chemistry (US), Office of Basic Energy Sciences (US)
Openalex Percentile: Top 1%
Carbon and Quantum Dots Applications
10.87
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