Analysis of Late Antique and Medieval Glass from Koper (Capodistria, SI): Insights into Glass Consumption and Production at the Turn of the First Millennium CE

A series (<i>n</i> = 22) of glasses from the site Kapucinski vrt (garden of the Capuchin monastery, 5th-17th c. CE) in Koper (Capodistria), a port town in the northern Adriatic, was measured using a combined PIXE and PIGE method. Koper has been continuously populated since the late Roman period, with a rich medieval history, thus offering an opportunity to study Early Medieval glass. Stemmed goblet fragments, in the original publication dated between the 6th-9th centuries CE, and several other vessel types (beakers and flasks or bottles and lamps) were selected for analysis. The measurements were expected to show the trends in glass production and consumption from Late Antiquity until the Middle Ages, notably the transition between natron to plant ash glass and the supply of fresh glass. Among the set of 22 glass vessel fragments, both natron and plant ash glass were identified. For finer classification, we relied on a newly developed method of Euclidean distances with respect to major concentrations. Natron glass of the types Foy 2.1 (9 examples), Magby (2 examples), and Levantine I (Apollonia; 2 examples) was found. Two glasses remain undetermined but testify to an Egyptian origin. Most natron glasses show signs of recycling. Among the three unrecycled glasses (about 20% of the whole set), there are two examples of Levantine glass and a Magby glass lamp; this may indicate a modest supply of fresh glass during the period. Plant ash glass may be attributed to the Early or High Middle Ages, exploiting the purified alkalis of the Levantine coasts (known as <i>alume catino</i> in later Venetian glassmaking), and the admixture of impurities in the siliceous sands suggests the circulation and consumption of glass that was produced and traded in the eastern Mediterranean since the 10th century CE.