Fluid Inclusion Evidence of Deep-Sourced Volatiles and Hydrocarbons Hosted in the F–Ba-Rich MVT Deposit Along the Zaghouan Fault (NE Tunisia)

The Hammam–Zriba F–Ba (Zn–Pb) stratabound deposit is located within the Zaghouan Fluorite Province (ZFP), which is the most important mineral sub-province in NE Tunisia, with several CaF2 deposits occurring mainly along the Zaghouan Fault and corresponding to an F-rich MVT mineral system developed along the unconformity surface between the uppermost Jurassic limestones and the late Cretaceous layers. Petrographic analysis, microthermometry, and Raman spectroscopy applied to fluid inclusions in fluorite revealed various types of inclusions containing brines, oil, CO2, and CH4 along with solid phases such as evenkite, graphite, kerogen and bitumen. Microthermometric data indicate homogenization temperatures ranging from 85 °C to 145 ± 5 °C and salinities of 13–22 wt.% NaCl equivalent. This study supports a model of heterogeneous trapping, where saline basinal brines, oil, and gases were simultaneously trapped within fluorite, which indicates fluid immiscibility. The Raman analysis identified previously undetected organic compounds, including the first documented occurrence of evenkite, a mineral hydrocarbon, co-genetically trapped with graphite. The identification of evenkite and graphite in fluid inclusions offers new insights into the composition of hydrocarbon-bearing fluids within the MVT deposits in Tunisia, contributing to an understanding of the mineralogical characteristics of these deposits. The identified hydrocarbons correspond to three oil families. Family I (aliphatic compounds) is attributed to the lower-Eocene Bou-Dabbous Formation, family II (aromatic compounds) is attributed to the Albian Fahdene Formation and the Cenomanian–Turonian Bahloul Formation, and family III is considered as a mixture of aliphatic and aromatic compounds generated by the three sources. The presence of graphite in fluid inclusions could suggest the involvement of a thermal effect from deep-seated sources through the reservoir to the site of fluorite precipitation. These findings suggest that the fluorite mineral system might have been linked with the interaction of multi-reservoir fluids, potentially linked to the neighboring petroleum system in northeastern Tunisia during the Miocene. This study aims to investigate the composition of fluid inclusions in fluorite from the Hammam–Zriba F–Ba (Zn–Pb) deposit, with a particular focus on the plausible sources of hydrocarbons and their implications for the genetic relationship between the mineralizing system and petroleum reservoirs.