Effects of fiber content on crystallization behavior and mechanical properties for fiber-reinforced microcellular injection molding combined with in-mold decoration process

• Mechanism of polymer crystallization in FR-MIM/IMD process is clarified. • Effect of fiber content on melt flow and microstructure in FR-MIM/IMD products is analyzed. • Fibers serve as heterogeneous nucleating agents, enhancing the crystallization behavior of FR-MIM/IMD products. • Incorporation of fibers enhances the mechanical properties of foamed products by optimizing their microstructure and crystallization. Fiber-reinforced microcellular injection molding combined with in-mold decoration (FR-MIM/IMD) is an emerging technique for producing lightweight polymer components with excellent mechanical performance and surface quality. However, unlike conventional injection molding (CIM), the FR-MIM/IMD process involves complex interactions among supercritical fluid, polymer melt, and reinforcing fibers, complicating the control of crystallization and structure–property development. In particular, the effects of varying fiber contents on melt behavior, cellular structure, and crystallization dynamics remains poorly understood. This study investigates how glass fiber (GF) content influences melt flow characteristics, microstructure, crystallization behavior, mechanical performance, and apparent density in nitrogen (N 2 )-foamed polypropylene (PP)/GF composites, using simulations and experiments. Results show that increasing fiber content elevates melt temperature, while viscosity peaks at 20 wt% before declining. Higher fiber content promotes fiber alignment, reduces cell size, increases cell density, and improves cell uniformity. Crystallization temperature rises with fiber content, although the crystallization rate slows. Both crystal size and β -crystal content peak at 20 wt%. Tensile and flexural strengths increase significantly—by 193.4 and 157.4% from 0 to 30 wt%, respectively—while elongation at break peaks at 10 wt%. Apparent density increases by 26.3%. These findings provide insights for optimizing FR-MIM/IMD processes and tailoring composite performance.

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Publication Details

Journal
Materials & Design
Published
2025-05-06
DOI
https://doi.org/10.1016/j.matdes.2025.114054
Citations
3
Primary Topic
Polymer Foaming and Composites
Type
article
Field-Weighted Citation Impact
1.82
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article

Effects of fiber content on crystallization behavior and mechanical properties for fiber-reinforced microcellular injection molding combined with in-mold decoration process

Lanyu Zeng, Qingzhou Li, Lei Xu, Shengrui Yu et al.
3 citations
Materials & Design
Polymer Foaming and Composites
1.82
article

Effects of fiber content on crystallization behavior and mechanical properties for fiber-reinforced microcellular injection molding combined with in-mold decoration process

Lanyu Zeng, Qingzhou Li, Lei Xu, Shengrui Yu, Chunfa Dong, Linan He, Fei Chen, Tianyu Zhang, Huamin Zhou, Han Wen, Haitao Hua, Senzhen Song
article en
3 citations

Abstract

• Mechanism of polymer crystallization in FR-MIM/IMD process is clarified. • Effect of fiber content on melt flow and microstructure in FR-MIM/IMD products is analyzed. • Fibers serve as heterogeneous nucleating agents, enhancing the crystallization behavior of FR-MIM/IMD products. • Incorporation of fibers enhances the mechanical properties of foamed products by optimizing their microstructure and crystallization. Fiber-reinforced microcellular injection molding combined with in-mold decoration (FR-MIM/IMD) is an emerging technique for producing lightweight polymer components with excellent mechanical performance and surface quality. However, unlike conventional injection molding (CIM), the FR-MIM/IMD process involves complex interactions among supercritical fluid, polymer melt, and reinforcing fibers, complicating the control of crystallization and structure–property development. In particular, the effects of varying fiber contents on melt behavior, cellular structure, and crystallization dynamics remains poorly understood. This study investigates how glass fiber (GF) content influences melt flow characteristics, microstructure, crystallization behavior, mechanical performance, and apparent density in nitrogen (N 2 )-foamed polypropylene (PP)/GF composites, using simulations and experiments. Results show that increasing fiber content elevates melt temperature, while viscosity peaks at 20 wt% before declining. Higher fiber content promotes fiber alignment, reduces cell size, increases cell density, and improves cell uniformity. Crystallization temperature rises with fiber content, although the crystallization rate slows. Both crystal size and β -crystal content peak at 20 wt%. Tensile and flexural strengths increase significantly—by 193.4 and 157.4% from 0 to 30 wt%, respectively—while elongation at break peaks at 10 wt%. Apparent density increases by 26.3%. These findings provide insights for optimizing FR-MIM/IMD processes and tailoring composite performance.

Materials & DesignVol. 254
Jingdezhen Ceramic Institute (CN), Huazhong University of Science and Technology (CN)
Sustainable cities and communities
Openalex Percentile: Top 16%
Polymer Foaming and Composites
1.82
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