Radiative Cooling of Long-Lived Molecular Negative Ions of Phenazine

Based on the harmonic cascade model, the rate constants of radiative cooling of the molecular negative ions of phenazine were calculated. It was determined that radiative cooling of molecular negative ions does not significantly affect the rates of electron autodetachment and makes no distortion to the results of measuring the negative ions lifetime by resonance electron capture mass spectrometry.

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Publication Details

Journal
Bulletin of the Russian Academy of Sciences Physics
Published
2025-03-01
DOI
https://doi.org/10.1134/s1062873824710092
Primary Topic
Photochemistry and Electron Transfer Studies
Type
article
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article

Radiative Cooling of Long-Lived Molecular Negative Ions of Phenazine

Р. В. Хатымов, М. В. Муфтахов, П. В. Щукин
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Bulletin of the Russian Academy of Sciences Physics
Photochemistry and Electron Transfer Studies
article

Radiative Cooling of Long-Lived Molecular Negative Ions of Phenazine

Р. В. Хатымов, М. В. Муфтахов, П. В. Щукин
article en

Abstract

Based on the harmonic cascade model, the rate constants of radiative cooling of the molecular negative ions of phenazine were calculated. It was determined that radiative cooling of molecular negative ions does not significantly affect the rates of electron autodetachment and makes no distortion to the results of measuring the negative ions lifetime by resonance electron capture mass spectrometry.

Bulletin of the Russian Academy of Sciences PhysicsVol. 89(3)
Russian Academy of Sciences (RU), D. Mendeleyev University of Chemical Technology of Russia (RU), Institute of Physics of Molecules and Crystals (RU)
Openalex Percentile: Top 90%
Photochemistry and Electron Transfer Studies
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