Non‐Aqueous Electrochemical CO <sub>2</sub> Reduction to Multivariate C <sub>2</sub> ‐Products Over Single Atom Catalyst at Current Density up to 100 mA cm <sup>−2</sup> (Small 18/2025)
CO2 Reduction In article number 2408010, Meenesh R. Singh and co-workers explore a conductive, stable Zr-based porphyrin metal–organic framework (MOF), PCN-222, metalated with single-atom Cu for CO2 reduction. PCN-222(Cu) achieves ∼100 mA cm−2 current density and 40% faradaic efficiency for acetate, outperforming previous MOF systems. X-ray and spectroscopic analyses provide key insights into its catalytic mechanism, advancing MOF-based single-atom catalysis.
Authors
- Meenesh R. Singh (ORCID: https://orcid.org/0000-0002-3638-8866)
- Michael L. Barsoum (ORCID: https://orcid.org/0000-0003-1161-764X)
- Rajan R. Bhawnani (ORCID: https://orcid.org/0000-0001-8536-2120)
- Rohan Sartape (ORCID: https://orcid.org/0000-0001-8975-4244)
- Vinayak P. Dravid (ORCID: https://orcid.org/0000-0002-6007-3063)
- Vamsi Vikram Gande (ORCID: https://orcid.org/0000-0001-7210-0033)
- Elias M. Kallon (ORCID: https://orcid.org/0000-0002-8637-9191)
- Roberto dos Reis (ORCID: https://orcid.org/0000-0002-6011-6078)
Institutions
- Northwestern University (US)
- University of Illinois Chicago (US)
Publication Details
- Journal
- Small
- Published
- 2025-05-01
- DOI
- https://doi.org/10.1002/smll.202570143
- Citations
- 1
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 0.36