Structural controls on lithium mineralization in shear-zone hosted granitic pegmatites of the Zulu pegmatite field, Zimbabwe – implications for exploration

Abstract Granitic pegmatites are a significant source of critical metals including tin, tantalum, and most notably lithium. To meet future demand, a comprehensive exploration model is required to assist in the discovery of new hard rock deposits. Whereas recent work has largely focused on understanding the source and mineralization processes of pegmatites, the structural controls on the distribution and size of individual deposits remains poorly understood and understudied. In this contribution, we present a structural study on the Zulu pegmatite field in Zimbabwe, which provides a good example of the influence of shear zones, host rock rheology, and lithological competency contrasts on the orientation, size, and distribution of pegmatite bodies within a pegmatite field. At Zulu, we observe both structural and petrographic evidence for two types of pegmatite emplacement within an active shear zone during D 2 strike-slip dominated deformation. An early generation (Type 1) was emplaced syn-kinematic to D 2 within dilational jogs subparallel to the shear fabric, and continued ductile shearing also drove significant recrystallization which affected the primary magmatic phases and therefore influenced the preserved mineralogy. A later generation (Type 2) was emplaced syn-to-late-kinematic to D 2 along tension gashes and subordinate fracture sets oblique to the shear fabric, which served to truncate the cooling history and preserve a primarily magmatic mineralogy within this pegmatite group. By comparing Zulu to other large pegmatite deposits, we conclude that geologic structures are critical to source-to-sink connectivity in lithium pegmatite systems, and affect the mineralization potential of individual deposits by driving recrystallization. Assessing the structural history and relative timing of emplacement within a pegmatite field, in conjunction with detailed (micro)textural observations from within pegmatite bodies, is essential to understanding pegmatite emplacement geometries. A more systematic approach in constraining these relationships will therefore aid in generating new exploration targets in both greenfield and brownfield settings.