Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1<i>H</i>-benzo[<i>d</i>]imidazole)

The asymmetric unit of the title compound, C<sub>20</sub>H<sub>22</sub>N<sub>4</sub>OS<sub>2</sub>, consists of two independent mol-ecules, one of which is disordered. In each mol-ecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetra-molecular strands are generated by C-H⋯N hydrogen bonds and C-H⋯π(ring) inter-actions and are linked by C-H⋯π(ring) and π-stacking inter-actions.

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2025-05-02
DOI
https://doi.org/10.1107/s2056989025003809
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)

Youssef Ramli, Ahmed Moussaif, Lhoussaine El Ghayati, El Mokhtar Essassi et al.
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
article

Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)

Youssef Ramli, Ahmed Moussaif, Lhoussaine El Ghayati, El Mokhtar Essassi, Camille Kalonji Mubengayi, Joel T. Mague, Abdulsalam Alsubari
article en

Abstract

The asymmetric unit of the title compound, C<sub>20</sub>H<sub>22</sub>N<sub>4</sub>OS<sub>2</sub>, consists of two independent mol-ecules, one of which is disordered. In each mol-ecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetra-molecular strands are generated by C-H⋯N hydrogen bonds and C-H⋯π(ring) inter-actions and are linked by C-H⋯π(ring) and π-stacking inter-actions.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 81(6)
Tulane University (US), Mohammed V University (MA), National Centre for Nuclear Energy, Science and Technology (MA), Institut Supérieur de Technique Médicale (CD)
Tulane University
Clean water and sanitation
Openalex Percentile: Top 92%
Crystal structures of chemical compounds
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Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1<i>H</i>-benzo[<i>d</i>]imidazole) — Youssef Ramli, Ahmed Moussaif, et al. · Acta Crystallographica Section E Crystallographic Communications (2025) | TGRS Research Map | TGRS