The Effect of Pore Functionality in Multicomponent Covalent Organic Frameworks on Stable Long‐Term Photocatalytic H <sub>2</sub> Production
Abstract In nature, organic molecules play a vital role in light harvesting and photosynthesis. However, regarding artificial water splitting, the research focus is primarily on inorganic semiconductors. Although organic photocatalysts have high structural variability, they tend to exhibit lower quantum efficiencies for water splitting than their inorganic counterparts. Multicomponent reactions (MCRs) offer an attractive route to introduce different functional units into covalent organic frameworks (COFs) and enable semiconducting properties and high chemical stability, creating promising materials for long‐term photocatalytic applications, such as H 2 production. Herein, five highly crystalline donor‐acceptor based, 4‐substituted quinoline‐linked MCR‐COFs are presented that are prepared via the three‐component Povarov reaction. The pore functionality is varied by applying different vinyl derivatives (e.g., styrene, 2‐vinyl pyridine, 4‐vinylpyridine, 4‐vinyl imidazole, 2,3,4,5,6‐pentafluorostyrene), which has a strong influence on the obtained photocatalytic activity. Especially an imidazole‐functionalized COF displays promising photocatalytic performance due to its high surface area, crystallinity, and wettability. These properties enable it to maintain its photocatalytic activity even in a membrane support. Furthermore, such MCR‐COFs display dramatically enhanced (photo)chemical stability even after long‐term solar light irradiation and exhibit a high and steady H 2 evolution for at least 15 days.
Authors
- Vincent Weigelt (ORCID: https://orcid.org/0009-0005-3749-6614)
- Christopher Penschke (ORCID: https://orcid.org/0000-0002-0117-7479)
- Gouri Chakraborty
- Jabor Rabeah (ORCID: https://orcid.org/0000-0003-2162-0981)
- Jérôme Roeser
- Michael Schwarze (ORCID: https://orcid.org/0000-0002-5632-603X)
- Hüseyin Küçükkeçeci (ORCID: https://orcid.org/0000-0002-7295-3084)
- Islam E. Khalil (ORCID: https://orcid.org/0000-0002-7240-5686)
- Shengjun Du (ORCID: https://orcid.org/0000-0003-0383-3318)
- Prasenjit Das (ORCID: https://orcid.org/0009-0006-1288-6736)
- Peter Saalfrank (ORCID: https://orcid.org/0000-0002-5988-5945)
- Martin Oschatz (ORCID: https://orcid.org/0000-0003-2377-1214)
- Johannes Schmidt (ORCID: https://orcid.org/0000-0002-9252-253X)
- Franziska Emmerling (ORCID: https://orcid.org/0000-0001-8528-0301)
- Nguyễn Anh Dũng (ORCID: https://orcid.org/0000-0003-4757-9809)
- Arne Thomas (ORCID: https://orcid.org/0000-0002-2130-4930)
- Jin Yang (ORCID: https://orcid.org/0000-0003-2937-4201)
- Reinhard Schomäcker
- José Gabriel
Institutions
- Helmholtz Institute Jena (DE)
- Federal Institute For Materials Research and Testing (DE)
- University of Potsdam (DE)
- Chinese Academy of Sciences (CN)
- Lanzhou Institute of Chemical Physics (CN)
- Leibniz Institute for Catalysis (DE)
- Technische Universität Berlin (DE)
- Friedrich Schiller University Jena (DE)
Publication Details
- Journal
- Advanced Energy Materials
- Published
- 2025-05-02
- DOI
- https://doi.org/10.1002/aenm.202501193
- Citations
- 8
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 4.14
Funders
- Alexander von Humboldt-Stiftung
- Deutsche Forschungsgemeinschaft
- Bundesministerium für Bildung und Forschung
- International Max Planck Research School for Advanced Methods in Process and Systems Engineering