The Component Composition of Fluid Phase during Crystallization of Subcalcic Chromium Garnet at High Pressure

The results of experimental modeling of the crystallization conditions for subcalcic Cr-rich garnets in the serpentine – chromite – carbonatite system at a pressure of 5 GPa and a temperature of 1300°C are presented. A mineral association of highly magnesian olivine and orthopyroxene, garnet and chrome-spinel is formed in the experiments. It has been established that subcalcic Cr-pyrope can crystallize in the form of metacrystals during metasomatism as a result of infiltration of the fluid phase. In the presence of graphite, the fluid phase has a complex composition with predominance of hydrocarbons and oxygen-, nitrogen-, and sulfur-containing organic compounds with minor amounts of inorganic gases, including CO2 and H2O.

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Publication Details

Journal
Doklady Earth Sciences
Published
2025-05-01
DOI
https://doi.org/10.1134/s1028334x25605772
Primary Topic
Mineralogy and Gemology Studies
Type
article
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article

The Component Composition of Fluid Phase during Crystallization of Subcalcic Chromium Garnet at High Pressure

Т. А. Бульбак, А. А. Томиленко, V. V. Lin, А. А. Чепуров et al.
Doklady Earth Sciences
Mineralogy and Gemology Studies
article

The Component Composition of Fluid Phase during Crystallization of Subcalcic Chromium Garnet at High Pressure

Т. А. Бульбак, А. А. Томиленко, V. V. Lin, А. А. Чепуров, В. М. Сонин, N. P. Pokhilenko, А. И. Чепуров, Е. И. Жимулев
article en

Abstract

The results of experimental modeling of the crystallization conditions for subcalcic Cr-rich garnets in the serpentine – chromite – carbonatite system at a pressure of 5 GPa and a temperature of 1300°C are presented. A mineral association of highly magnesian olivine and orthopyroxene, garnet and chrome-spinel is formed in the experiments. It has been established that subcalcic Cr-pyrope can crystallize in the form of metacrystals during metasomatism as a result of infiltration of the fluid phase. In the presence of graphite, the fluid phase has a complex composition with predominance of hydrocarbons and oxygen-, nitrogen-, and sulfur-containing organic compounds with minor amounts of inorganic gases, including CO2 and H2O.

Doklady Earth SciencesVol. 522(2)
V.S. Sobolev Institute of Geology and Mineralogy (RU)
Openalex Percentile: Top 91%
Mineralogy and Gemology Studies
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The Component Composition of Fluid Phase during Crystallization of Subcalcic Chromium Garnet at High Pressure — Т. А. Бульбак, А. А. Томиленко, et al. · Doklady Earth Sciences (2025) | TGRS Research Map | TGRS