Using Salinity, Water Level, CFCs, and CCl4 to Assess Groundwater Flow Dynamics and Potential N2O Flux in the Intertidal Zone of Sanya, Hainan Province: Implications for Evaluating Freshwater Submarine Groundwater Discharge in Coastal Unconfined Aqui

This study combines field and laboratory analyses from seven shallow wells (ZK1 to ZK7) positioned perpendicular to the coastline to investigate groundwater discharge and dynamics in the coastal unconfined aquifer of the intertidal zone at Yazhou Bay, Sanya, Hainan Province. The research highlights spatial variations in N2O concentration, temperature, electrical conductivity (EC), pH, and the distribution of CFCs and CCl4 in shallow groundwater, utilizing samples from wells ZK1 to ZK7 and seawater collected near ZK1. Key findings indicate that groundwater temperature decreases toward the ocean, while EC exhibits a stepwise increase from land to sea, with a sharp transition near ZK3 marking the freshwater–saltwater mixing zone. pH values are lowest in ZK3 and ZK4, gradually rising both inland and seaward. N2O concentrations in the shallow wells (ZK1–ZK7) are divided into two distinct groups: higher concentrations (9.69–57.77 nmol/kg) in ZK5–ZK7 and lower concentrations (6.63–23.03 nmol/kg) in ZK1–ZK4. Wells ZK3 and ZK4 show minimal variation in CFC-11 and CFC-113 concentrations, suggesting they represent a transition zone that likely delineates groundwater flow paths. In contrast, significant concentration differences in wells ZK5–ZK7 (north) and ZK1–ZK2 (south) reflect the influence of aquifer structure variability, recharge sources, and local hydrogeochemical conditions. CFC-12 concentrations exhibit a clear freshwater–saltwater mixing gradient between ZK3 and ZK1, with higher concentrations in freshwater-dominated areas (ZK3–ZK7) and lower concentrations near seawater (ZK1). CCl4 concentrations at ZK7 and ZK3 differ markedly from other wells, indicating unique hydrogeochemical conditions or localized anthropogenic influences. A model for the formation of upper saline plumes (USP) under tidal forcing at the low tidal line was established previously. Here, we establish a new model that accounts for the absence of USP driven by hydrological processes influenced by artificial sandy beach topography, and a fresh groundwater wedge is identified, which can serve as a significant fast-flow pathway for terrestrial water and nutrients to the ocean.