Viscous liquid dynamics modeled as random walks within overlapping hyperspheres

The hypersphere model is a simple one-parameter model of the potential-energy landscape of viscous liquids, which is defined as a percolating system of same-radius hyperspheres randomly distributed in R^{3N}, in which N is the number of particles. We study random walks within overlapping hyperspheres above the percolation threshold in 12 to 45 dimensions, utilizing an algorithm for on-the-fly placement of the hyperspheres in conjunction with the kinetic Monte Carlo method. We find behavior typical of viscous liquids; decreasing the hypersphere density (corresponding to decreasing the temperature) leads to a slowing down of the dynamics by many orders of magnitude. The shape of the mean-square displacement as a function of time is found to be similar to that of the Kob-Andersen binary Lennard-Jones mixture and the random barrier model, which predicts well the frequency-dependent fluidity of nine glass-forming liquids of different chemistry [Bierwirth et al., Phys. Rev. Lett. 119, 248001 (2017)0031-900710.1103/PhysRevLett.119.248001].

Authors

Institutions

Publication Details

Journal
Physical review. E
Published
2025-05-01
DOI
https://doi.org/10.1103/physreve.111.055301
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.00

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Viscous liquid dynamics modeled as random walks within overlapping hyperspheres

Thomas B. Schrøder, Jeppe C. Dyre, Mark F. B. Railton, Eva Uhre
Physical review. E
Material Dynamics and Properties
article

Viscous liquid dynamics modeled as random walks within overlapping hyperspheres

Thomas B. Schrøder, Jeppe C. Dyre, Mark F. B. Railton, Eva Uhre
article en

Abstract

The hypersphere model is a simple one-parameter model of the potential-energy landscape of viscous liquids, which is defined as a percolating system of same-radius hyperspheres randomly distributed in R^{3N}, in which N is the number of particles. We study random walks within overlapping hyperspheres above the percolation threshold in 12 to 45 dimensions, utilizing an algorithm for on-the-fly placement of the hyperspheres in conjunction with the kinetic Monte Carlo method. We find behavior typical of viscous liquids; decreasing the hypersphere density (corresponding to decreasing the temperature) leads to a slowing down of the dynamics by many orders of magnitude. The shape of the mean-square displacement as a function of time is found to be similar to that of the Kob-Andersen binary Lennard-Jones mixture and the random barrier model, which predicts well the frequency-dependent fluidity of nine glass-forming liquids of different chemistry [Bierwirth et al., Phys. Rev. Lett. 119, 248001 (2017)0031-900710.1103/PhysRevLett.119.248001].

Physical review. EVol. 111(5)
Roskilde University (DK)
Villum Fonden
Climate action
Openalex Percentile: Top 94%
Material Dynamics and Properties
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Viscous liquid dynamics modeled as random walks within overlapping hyperspheres — Thomas B. Schrøder, Jeppe C. Dyre, et al. · Physical review. E (2025) | TGRS Research Map | TGRS