Photosensitized Imino-Sulfamoylation of Alkenes with Oxime Carbamates
In this study, we have devised a strategy that employs oxime carbamate as a bifunctional diamination reagent in combination with SO<sub>2</sub> to realize imino-sulfamoylation of alkenes. This protocol is characterized by its mild conditions, operational simplicity, and metal-free nature, while demonstrating broad functional group tolerance for alkenes. Furthermore, the application of this method provides an accessible route to a diverse range of β-amino sulfonamide derivatives.
Authors
- Peng‐Fei Xu (ORCID: https://orcid.org/0000-0002-5746-758X)
- Ai-Lian Wang
- Huan-Huan Zhao (ORCID: https://orcid.org/0009-0003-1361-4482)
- Haowen Jiang
Institutions
- State Key Laboratory of Chemical Engineering (CN)
- Lanzhou University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-05-01
- DOI
- https://doi.org/10.1021/acs.orglett.5c01128
- Citations
- 2
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- National Natural Science Foundation of China
- Science and Technology Department of Gansu Province
- Higher Education Discipline Innovation Project
- Science and Technology Department of Xinjiang Uyghur Autonomous Region