Catalytic Aspects of Liquid Organic Hydrogen Carrier Technology

The surge in photovoltaic (PV) power generation has made it increasingly difficult to integrate the intermittent PV industry into the power grid while maintaining grid stability. The solution is to use the seasonal surplus of PV electricity to produce “green” hydrogen through water electrolysis and then use the hydrogen as an energy source or as a reactant in chemical processes in the chemical industry to produce value-added products. However, the development of advanced hydrogen storage technologies to ensure the safe handling, transportation, and distribution of H2 is a major issue. The use of stable liquid organic hydrogen carriers (LOHCs) has emerged as a suitable technology for hydrogen storage. This review highlights prospective LOHC technologies based on reversible catalytic hydrogenation–dehydrogenation cycles of liquid organic molecules for hydrogen storage and release under mild temperature and pressure conditions. The state-of-the-art LOHC systems are critically reviewed, highlighting the most effective heterogeneous catalytic systems.