Cold Uniaxial Pressing of PTFE-Based Composite Materials with Functional TiC and TiB2 Additives

The possibilities of a solid-phase technology to produce composite materials based on polymer mixtures of PN-90 polytetrafluoroethylene (PTFE) with functional additives of titanium carbide and diboride synthesized by self-propagating high-temperature synthesis (SHS) are studied. The pressing of bulk-density composite powders into compact billets in a special mold by loading at a constant speed is studied. Rheological stress σ–strain ε curves are obtained and used to determine the time of the beginning of a progressive increase in stress inside a sample. The experimental results are compared with the data obtained for samples without additives (pure PTFE) and for compositions with a basalt fiber (BF). At a stress of 171–177 MPa, the density corresponding to a calculated compact density of 2.24–2.25 g/cm3 is shown to be achieved. The density difference throughout the volume of a compact sample is investigated, and a comparative analysis of compressibility moduli G after uniaxial cold pressing is performed.

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Publication Details

Journal
Russian Metallurgy (Metally)
Published
2024-09-01
DOI
https://doi.org/10.1134/s0036029525700387
Primary Topic
Material Properties and Applications
Type
article
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article

Cold Uniaxial Pressing of PTFE-Based Composite Materials with Functional TiC and TiB2 Additives

А. М. Столин, Aitalina Alekseevna Okhlopkova, P. A. Stolin, Nadezhda Nikolaevna Lazareva et al.
Russian Metallurgy (Metally)
Material Properties and Applications
article

Cold Uniaxial Pressing of PTFE-Based Composite Materials with Functional TiC and TiB2 Additives

А. М. Столин, Aitalina Alekseevna Okhlopkova, P. A. Stolin, Nadezhda Nikolaevna Lazareva, О. А. Аверичев
article en

Abstract

The possibilities of a solid-phase technology to produce composite materials based on polymer mixtures of PN-90 polytetrafluoroethylene (PTFE) with functional additives of titanium carbide and diboride synthesized by self-propagating high-temperature synthesis (SHS) are studied. The pressing of bulk-density composite powders into compact billets in a special mold by loading at a constant speed is studied. Rheological stress σ–strain ε curves are obtained and used to determine the time of the beginning of a progressive increase in stress inside a sample. The experimental results are compared with the data obtained for samples without additives (pure PTFE) and for compositions with a basalt fiber (BF). At a stress of 171–177 MPa, the density corresponding to a calculated compact density of 2.24–2.25 g/cm3 is shown to be achieved. The density difference throughout the volume of a compact sample is investigated, and a comparative analysis of compressibility moduli G after uniaxial cold pressing is performed.

Russian Metallurgy (Metally)Vol. 2024(9)
North-Eastern Federal University (RU), Institute of Structural Macrokinetics and Materials Science (RU)
Openalex Percentile: Top 49%
Material Properties and Applications
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