Stereoselective Synthesis of Monofluoroalkenes via Photoinduced Direct Monofluoroalkenylation of C(sp³)–H Bonds

Abstract In this study, a method is introduced for the photoinduced direct monofluoroalkenylation of C(sp³)–H bonds. A diverse range of fluoroacrylic acids react smoothly with various C–H substrates, leading to the formation of important monofluoroalkene motifs. Notably, this approach is cost-effective, exhibits high stereoselectivity, and eliminates the need for metal catalysts.