Green‐Light Cerium Photocatalysis Enabled by Pyridine N‐Oxide Ligands
Pyridine N‐oxides are reported as neutral ligands in cerium photocatalysis. By using those neutral ligands, photoactive Ce(IV)‐species are generated, which show an extensive bathochromic shift compared to previously employed cerium‐based complexes. This allows the effective utilization of green light in the redox‐neutral CH‐hydrazination of small molecules under very mild photocatalytic conditions.
Authors
- J Stahl (ORCID: https://orcid.org/0000-0003-2685-0962)
- Burkhard Koenig (ORCID: https://orcid.org/0000-0002-6131-4850)
- Nicolas Müller (ORCID: https://orcid.org/0000-0002-9505-2326)
- Julia Stoiber
Institutions
- University of Regensburg (DE)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2025-04-29
- DOI
- https://doi.org/10.1002/ejoc.202500373
- Citations
- 1
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.52
Funders
- Deutsche Forschungsgemeinschaft