The Thermo-Optic Discrimination of an Aqueous Solution Composition Using a Multimodal Interference Fiber Optic Sensor

Fiber optics sensors based on multimodal interference (MMI) have proven effective for refractometry of liquid samples. Here, we extend these capabilities to demonstrate that aqueous solutions with a similar refractive index (RI), which at room temperature are indistinguishable at the same concentration, can be discriminated against based on their thermo-optical response. We used an MMI sensor with the standard singlemode–multimode–singlemode architecture, where a section of no-core multimode fiber provides environmental sensitivity to the fiber surroundings. The proposed idea has been tested on aqueous solutions of tris and fructose, whose RI has a similar dependence on concentration. Indeed, we verified that they produce indistinguishable wavelength shifts as a function of concentration, measuring 0.2179 nm/% for tris and 0.2264 nm/% for fructose. Then, by varying the temperature in a controlled manner, from 25 °C to 45 °C in 2.5 °C increments, the distinct thermo-optic response can be unveiled for the two samples, which now permits differentiating them. Thermal sensitivities of 0.14433 nm/°C for tris and 0.1852 nm/°C for fructose were observed. This optical sensor requires no specific preparation or specialized equipment because the temperature range needed to achieve thermo-optical discrimination is accessible. Therefore, the measurement protocol can be incorporated into commercial refractometers equipped with temperature control.