Zinc Chalcogenide Based Shell Layers for Colloidal Quantum Wells

Abstract Colloidal quantum wells, also known as colloidal nanoplatelets (NPLs), have emerged as a promising class of materials for light‐emitting devices (LEDs). However, the most widely studied core/shell NPLs, which rely on cadmium‐based shell layers, face challenges due to toxicity concerns and improper charge confinement. To address these limitations, a new synthetic approach is presented that enables the controlled growth of zinc chalcogenide‐based shell layers on NPLs. The synthesized CdSe/ZnSe core/shell NPLs exhibit emission between 615 and 630 nm, with a moderate photoluminescence quantum yield (PL‐QY) of 40–50%. It is also demonstrated that the lateral dimensions of the CdSe core NPLs significantly affect the optical properties of the core/shell heterostructures, with smaller lateral dimensions resulting in narrower emission linewidths as low as 20 nm. Further passivation of these core/shell NPLs with an additional ZnS shell layer significantly increases the PL‐QY up to 80–90%. Finally, the device performance of these two core/shell NPLs is investigated by fabricating solution‐processed LEDs. With LEDs incorporating CdSe/ZnSe/ZnS core/multi‐shell NPLs as the active light‐emitting layer, an external quantum efficiency (EQE) of 3.82% and a maximum brightness of 6477 cd m − 2 is obtained. These findings underscore the significant potential of zinc chalcogenide‐based shell layers in advancing colloidal NPLs toward high‐performance light‐emitting devices.