Investigation of FPM as a Corrosion Inhibitor for Mild Steel in HCl Solution: Insights from Electrochemical, Weight loss and Theoretical Approaches

In this study, we investigate the efficiency of furan-2-yl-piperazin-1-yl-methanone (FPM) as a corrosion inhibitor for mild steel in HCl environment. Our study combines electrochemical techniques, weight loss measurements and Density Functional Theory (DFT) calculations. Regarding weight loss experiments, we find that a concentration of 0.5 mM of FPM provides maximum protection efficacy, reaching 91.8% at 303 K after 30 minutes of immersion and observed that the inhibition efficiency rises with increasing concentration of FPM but declines with higher temperatures. Based on the Langmuir isotherm and experimental analysis, it can be suggested that FPM can adhere to the surface of mild steel through physical and chemical interactions. Moreover, our theoretical studies reveals correlations between the structure of FPM and its effectiveness in inhibiting corrosion, shedding light on the underlying mechanisms. Experimental and theoretical results both are in agreement. Our findings underscore the potential of FPM as a corrosion inhibitor in industrial applications, offering new avenues for corrosion control techniques.

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Publication Details

Journal
Zastita materijala
Published
2025-04-27
DOI
https://doi.org/10.62638/zasmat1047
Primary Topic
Corrosion Behavior and Inhibition
Type
article
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article

Investigation of FPM as a Corrosion Inhibitor for Mild Steel in HCl Solution: Insights from Electrochemical, Weight loss and Theoretical Approaches

Firas Farhan Sayyid, Ahmed A. Al‐Amiery, Hakim S. Sultan Aljibori, S Ahmed et al.
Zastita materijala
Corrosion Behavior and Inhibition
article

Investigation of FPM as a Corrosion Inhibitor for Mild Steel in HCl Solution: Insights from Electrochemical, Weight loss and Theoretical Approaches

Firas Farhan Sayyid, Ahmed A. Al‐Amiery, Hakim S. Sultan Aljibori, S Ahmed, Ali Mundher Mustafa, Najeb Salman Abtan, A Alwazir, Abdul Amir H. Kadhum
article en

Abstract

In this study, we investigate the efficiency of furan-2-yl-piperazin-1-yl-methanone (FPM) as a corrosion inhibitor for mild steel in HCl environment. Our study combines electrochemical techniques, weight loss measurements and Density Functional Theory (DFT) calculations. Regarding weight loss experiments, we find that a concentration of 0.5 mM of FPM provides maximum protection efficacy, reaching 91.8% at 303 K after 30 minutes of immersion and observed that the inhibition efficiency rises with increasing concentration of FPM but declines with higher temperatures. Based on the Langmuir isotherm and experimental analysis, it can be suggested that FPM can adhere to the surface of mild steel through physical and chemical interactions. Moreover, our theoretical studies reveals correlations between the structure of FPM and its effectiveness in inhibiting corrosion, shedding light on the underlying mechanisms. Experimental and theoretical results both are in agreement. Our findings underscore the potential of FPM as a corrosion inhibitor in industrial applications, offering new avenues for corrosion control techniques.

Zastita materijalaVol. 66(3)
University of Technology - Iraq (IQ), University of Kerbala (IQ), University of Warith Al-Anbiyaa, University of Tikrit (IQ), National University of Malaysia (MY)
Openalex Percentile: Top 94%
Corrosion Behavior and Inhibition
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Investigation of FPM as a Corrosion Inhibitor for Mild Steel in HCl Solution: Insights from Electrochemical, Weight loss and Theoretical Approaches — Firas Farhan Sayyid, Ahmed A. Al‐Amiery, et al. · Zastita materijala (2025) | TGRS Research Map | TGRS