The role of coal components and modifications on direct carbon fuel cells

Direct carbon fuel cells are a type of high-temperature fuel cells with great potential. Compared to traditional coal-fired power stations, they offer higher efficiency and lower emissions, enabling the efficient and clean use of coal. The modification of coal with acetic acid, HCl, and NaOH improves the output performance of coal in a molten carbonate direct carbon fuel cell. The electrochemical performance of modified coal is related to its chemical composition, the concentration of oxygen-containing surface functional groups, and ash components. Electrochemical performance tests were conducted using SG, SG-Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>, SG-CaCO<sub>3</sub>, and SG-FeS<sub>2</sub> as anode fuels for molten carbonate direct carbon fuel cells and hybrid direct carbon fuel cells. Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub> had no significant effect on the power density of DCFC. Both CaCO<sub>3</sub> and FeS<sub>2</sub> could enhance the polarization performance of the battery but would affect the current density during battery discharge.

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Published
2025-04-25
DOI
https://doi.org/10.1117/12.3067313
Primary Topic
Coal and Coke Industries Research
Type
article
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article

The role of coal components and modifications on direct carbon fuel cells

Yue Ding, Jing Zhao, Jiaxin Yao, Xuan Zhang et al.
Coal and Coke Industries Research
article

The role of coal components and modifications on direct carbon fuel cells

Yue Ding, Jing Zhao, Jiaxin Yao, Xuan Zhang, Qing Wen, Guiling Wang, Xianchao Wang, Jinling Yin
article en

Abstract

Direct carbon fuel cells are a type of high-temperature fuel cells with great potential. Compared to traditional coal-fired power stations, they offer higher efficiency and lower emissions, enabling the efficient and clean use of coal. The modification of coal with acetic acid, HCl, and NaOH improves the output performance of coal in a molten carbonate direct carbon fuel cell. The electrochemical performance of modified coal is related to its chemical composition, the concentration of oxygen-containing surface functional groups, and ash components. Electrochemical performance tests were conducted using SG, SG-Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>, SG-CaCO<sub>3</sub>, and SG-FeS<sub>2</sub> as anode fuels for molten carbonate direct carbon fuel cells and hybrid direct carbon fuel cells. Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub> had no significant effect on the power density of DCFC. Both CaCO<sub>3</sub> and FeS<sub>2</sub> could enhance the polarization performance of the battery but would affect the current density during battery discharge.

Harbin Engineering University (CN), Institute of New Materials (CN), Nano Carbon (Poland) (PL)
Openalex Percentile: Top 86%
Coal and Coke Industries Research
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