Hydrothermal Liquefaction (HTL) of Lignin: The Adsorption Separation of Catechol Guaiacol and Phenol

The complex nature of the hydrothermal liquefaction (HTL) of lignin product downstream requires an effective separation strategy. In this study, the use of adsorption separation was undertaken using deep eutectic solvent (DES)-modified amberlite XAD-4 adsorbents to achieve this goal. XAD-4 was modified with a choline chloride: ethylene glycol DES and characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and the Brunauer–Emmett–Teller (BET) test. In addition, the HTL product was characterized using Gas Chromatography with Flame Ionization Detection (GC-FID). The performance of unmodified and DES-modified adsorbents was initially tested on the model compounds of guaiacol, phenol and catechol, followed by the HTL product in a batch adsorption system. The Freundlich model best described the model compound adsorption system with a preferential affinity for guaiacol (kf = 12.52), outperforming phenol and catechol. Adsorption experiments showed an increase in capacity and selectivity for all species when the DES-modified adsorbents were used at all mass loadings. GC-FID analytics showed the DES-modified XAD-4 (300 mg) as having the highest selectivity for guaiacol, with an equilibrium concentration of 121.45 mg/L representing an 85.25% uptake, while catechol was the least favorably adsorbed. These results demonstrate the potential of DES-functionalized XAD-4 adsorbents in selectively isolating high-value aromatics from the HTL of the lignin product stream.