Palladium/Palladium Oxide Nanosheet Heterostructures by Partial Reduction for Sub-Parts per Million Hydrogen Detection at Room Temperature
To address the energy crisis and mitigate greenhouse gas emissions, substantial investments are advancing hydrogen (H2) technologies. Reliable, efficient room-temperature H2 sensors are critical for ensuring safe H2 production and utilization. Here, we report a palladium/palladium oxide (Pd/PdO) nanosheet composite capable of detecting H2 concentrations as low as 0.5 ppm at room temperature. The sensor exhibits exceptional stability, maintaining this detection limit after four months under ambient conditions. The superior H2 sensing performance stems from two key features: (1) the ultrathin nanosheet morphology, which offers abundant reactive sites, and (2) Pd nanoregions that enhance chemical and electronic sensitization. Together, these attributes synergistically elevate room-temperature H2 detection. This work demonstrates a promising strategy for advancing H2 sensor performance, supporting the transition to a hydrogen-based economy.
Authors
- Rui Yang (ORCID: https://orcid.org/0000-0003-3860-7206)
- Jian Wu (ORCID: https://orcid.org/0000-0003-3747-7358)
- Jaafar Abdul‐Aziz Mehrez (ORCID: https://orcid.org/0000-0002-4784-7052)
- Min Zeng (ORCID: https://orcid.org/0000-0003-3594-7619)
- Nantao Hu (ORCID: https://orcid.org/0000-0001-9420-1329)
- J. Joshua Yang (ORCID: https://orcid.org/0000-0001-8242-7531)
- Hao Zhu (ORCID: https://orcid.org/0009-0001-1290-3675)
- Zhi Yang (ORCID: https://orcid.org/0000-0002-0871-5882)
- Yuyang Wang (ORCID: https://orcid.org/0000-0003-4109-5379)
- Xiao Li (ORCID: https://orcid.org/0000-0001-7647-717X)
- Xue Liu (ORCID: https://orcid.org/0000-0002-6607-5326)
- Yaozong Zhai
Institutions
- Shanghai Jiao Tong University (CN)
- Micro & Nano Research Institute (CN)
- Innovation Academy for Microsatellites of Chinese Academy of Sciences
Publication Details
- Journal
- ACS Applied Nano Materials
- Published
- 2025-04-24
- DOI
- https://doi.org/10.1021/acsanm.5c01235
- Primary Topic
- Gas Sensing Nanomaterials and Sensors
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Natural Science Foundation of Shanghai
- National Natural Science Foundation of China
- National Key Research and Development Program of China