Crystal structure of a bis-4-azatetracyclo[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione compound
In the molecule of 4-({3-[(3,5-dioxo-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-en-4-yl)meth-yl]phen-yl}meth-yl)-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione, C<sub>30</sub>H<sub>28</sub>N<sub>2</sub>O<sub>4</sub>, which contains two substituted [2.2.2]bi-cyclo-octene ring systems linked through a <i>m</i>-xylenedi-amine ring, the six-membered rings of the bi-cyclo-octene ring systems adopt nearly perfect boat conformations as determined from Cremer-Pople analysis. Both ring systems are fused to a five-membered imide ring that is oriented <i>endo</i> to a bridgehead cyclo-propyl ring. The crystal structure features C=O⋯π inter-actions along with C-H⋯O hydrogen bonds.
Authors
- C. Jiang (ORCID: https://orcid.org/0009-0003-6220-069X)
- Richard J. Staples (ORCID: https://orcid.org/0000-0003-2760-769X)
- Shannon M. Biros (ORCID: https://orcid.org/0000-0002-9676-2741)
Institutions
- Grand Valley State University (US)
- Michigan State University (US)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2025-04-24
- DOI
- https://doi.org/10.1107/s2056989025003500
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Grand Valley State University