Crystal structure of a bis-4-azatetracyclo[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione compound

In the molecule of 4-({3-[(3,5-dioxo-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-en-4-yl)meth-yl]phen-yl}meth-yl)-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione, C<sub>30</sub>H<sub>28</sub>N<sub>2</sub>O<sub>4</sub>, which contains two substituted [2.2.2]bi-cyclo-octene ring systems linked through a <i>m</i>-xylenedi-amine ring, the six-membered rings of the bi-cyclo-octene ring systems adopt nearly perfect boat conformations as determined from Cremer-Pople analysis. Both ring systems are fused to a five-membered imide ring that is oriented <i>endo</i> to a bridgehead cyclo-propyl ring. The crystal structure features C=O⋯π inter-actions along with C-H⋯O hydrogen bonds.

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2025-04-24
DOI
https://doi.org/10.1107/s2056989025003500
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

Crystal structure of a bis-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione compound

C. Jiang, Richard J. Staples, Shannon M. Biros
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
article

Crystal structure of a bis-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione compound

C. Jiang, Richard J. Staples, Shannon M. Biros
article en

Abstract

In the molecule of 4-({3-[(3,5-dioxo-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-en-4-yl)meth-yl]phen-yl}meth-yl)-4-aza-tetra-cyclo-[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione, C<sub>30</sub>H<sub>28</sub>N<sub>2</sub>O<sub>4</sub>, which contains two substituted [2.2.2]bi-cyclo-octene ring systems linked through a <i>m</i>-xylenedi-amine ring, the six-membered rings of the bi-cyclo-octene ring systems adopt nearly perfect boat conformations as determined from Cremer-Pople analysis. Both ring systems are fused to a five-membered imide ring that is oriented <i>endo</i> to a bridgehead cyclo-propyl ring. The crystal structure features C=O⋯π inter-actions along with C-H⋯O hydrogen bonds.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 81(5)
Grand Valley State University (US), Michigan State University (US)
Grand Valley State University
Openalex Percentile: Top 93%
Crystal structures of chemical compounds
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