Three types of condensation in open wedges

Condensation in linear wedges formed by semi-infinite walls is a well-established critical phenomenon characterized by the continuous growth of an adsorbed liquid layer as bulk two-phase coexistence is approached. In this study, we investigate condensation in finite-length wedges open at both ends, demonstrating that the process becomes first-order. The open boundaries and finite geometry induce a remarkably rich phase behavior of the confined fluid, exhibiting three distinct types of condensation, reentrant phenomena, and continuous higher-order transitions between condensation states. Through a detailed macroscopic analysis, we derive the conditions for each type of condensation, classify the global phase diagrams, and explore asymptotic behavior in specific limiting cases. The asymptotic predictions are confirmed by a detailed comparison with the numerical solutions of the governing equations.

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Publication Details

Journal
Physical review. E
Published
2025-04-23
DOI
https://doi.org/10.1103/physreve.111.045507
Citations
1
Primary Topic
nanoparticles nucleation surface interactions
Type
article
Field-Weighted Citation Impact
1.30
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article

Three types of condensation in open wedges

Jiří Janek, Alexandr Malijevský
1 citations
Physical review. E
nanoparticles nucleation surface interactions
1.30
article

Three types of condensation in open wedges

Jiří Janek, Alexandr Malijevský
article en
1 citations

Abstract

Condensation in linear wedges formed by semi-infinite walls is a well-established critical phenomenon characterized by the continuous growth of an adsorbed liquid layer as bulk two-phase coexistence is approached. In this study, we investigate condensation in finite-length wedges open at both ends, demonstrating that the process becomes first-order. The open boundaries and finite geometry induce a remarkably rich phase behavior of the confined fluid, exhibiting three distinct types of condensation, reentrant phenomena, and continuous higher-order transitions between condensation states. Through a detailed macroscopic analysis, we derive the conditions for each type of condensation, classify the global phase diagrams, and explore asymptotic behavior in specific limiting cases. The asymptotic predictions are confirmed by a detailed comparison with the numerical solutions of the governing equations.

Physical review. EVol. 111(4)
Czech Academy of Sciences, Institute of Chemical Process Fundamentals (CZ), University of Chemistry and Technology, Prague (CZ)
Openalex Percentile: Top 24%
nanoparticles nucleation surface interactions
1.30
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