Negative thermodynamic pressure: No-go theorem and yes-go examples

Theory and experiment have long discussed negative thermodynamic pressure states, but their microscopic origins are unclear. I address this problem within the framework of quantum thermodynamics. I show that the pressure exerted on the boundary is positive when there is no interaction with the boundary. This is formalized by a no-go theorem that holds for any quantum state with finite motion. As a consequence of this analysis, I deduce a general formula for quantum nonequilibrium pressure. It is believed that stable negative pressure states cannot exist in gases. I provide solvable examples of quantum and classical gases, where negative pressure is achieved due to a suitable coupling with the boundary walls.

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Publication Details

Journal
Physical review. E
Published
2025-04-22
DOI
https://doi.org/10.1103/physreve.111.l042105
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
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article

Negative thermodynamic pressure: No-go theorem and yes-go examples

V. A. Stepanyan
Physical review. E
Advanced Thermodynamics and Statistical Mechanics
article

Negative thermodynamic pressure: No-go theorem and yes-go examples

V. A. Stepanyan
article en

Abstract

Theory and experiment have long discussed negative thermodynamic pressure states, but their microscopic origins are unclear. I address this problem within the framework of quantum thermodynamics. I show that the pressure exerted on the boundary is positive when there is no interaction with the boundary. This is formalized by a no-go theorem that holds for any quantum state with finite motion. As a consequence of this analysis, I deduce a general formula for quantum nonequilibrium pressure. It is believed that stable negative pressure states cannot exist in gases. I provide solvable examples of quantum and classical gases, where negative pressure is achieved due to a suitable coupling with the boundary walls.

Physical review. EVol. 111(4)
Yerevan State University (AM)
Openalex Percentile: Top 93%
Advanced Thermodynamics and Statistical Mechanics
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