Negative thermodynamic pressure: No-go theorem and yes-go examples
Theory and experiment have long discussed negative thermodynamic pressure states, but their microscopic origins are unclear. I address this problem within the framework of quantum thermodynamics. I show that the pressure exerted on the boundary is positive when there is no interaction with the boundary. This is formalized by a no-go theorem that holds for any quantum state with finite motion. As a consequence of this analysis, I deduce a general formula for quantum nonequilibrium pressure. It is believed that stable negative pressure states cannot exist in gases. I provide solvable examples of quantum and classical gases, where negative pressure is achieved due to a suitable coupling with the boundary walls.
Authors
- V. A. Stepanyan (ORCID: https://orcid.org/0000-0001-8819-9226)
Institutions
- Yerevan State University (AM)
Publication Details
- Journal
- Physical review. E
- Published
- 2025-04-22
- DOI
- https://doi.org/10.1103/physreve.111.l042105
- Primary Topic
- Advanced Thermodynamics and Statistical Mechanics
- Type
- article
- Field-Weighted Citation Impact
- 0.00