Photoinduced Copper‐Catalyzed N‐Arylation Reaction of NH Heteroarenes Using Aryl Thianthrenium Salts

Herein, an efficient photoinduced copper‐catalyzed N‐arylation reaction is presented, which occurs through the cross‐coupling of NH heteroarenes with aryl thianthrenium salts (Ar‐TTs). This photoactivation strategy exhibits broad substrate scope and offers a method for preserving activated functional groups (such as Br, CHO, and CN) for subsequent derivatization reactions.

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Publication Details

Journal
European Journal of Organic Chemistry
Published
2025-04-22
DOI
https://doi.org/10.1002/ejoc.202500303
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
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article

Photoinduced Copper‐Catalyzed N‐Arylation Reaction of NH Heteroarenes Using Aryl Thianthrenium Salts

Mingming Gao, Lan Bao, Wei Liu, Qianqian Yang et al.
2 links
European Journal of Organic Chemistry
Catalytic C–H Functionalization Methods
article

Photoinduced Copper‐Catalyzed N‐Arylation Reaction of NH Heteroarenes Using Aryl Thianthrenium Salts

Mingming Gao, Lan Bao, Wei Liu, Qianqian Yang, Zhenhui Wang, Ruiyun Zhang
article en

Abstract

Herein, an efficient photoinduced copper‐catalyzed N‐arylation reaction is presented, which occurs through the cross‐coupling of NH heteroarenes with aryl thianthrenium salts (Ar‐TTs). This photoactivation strategy exhibits broad substrate scope and offers a method for preserving activated functional groups (such as Br, CHO, and CN) for subsequent derivatization reactions.

European Journal of Organic ChemistryVol. 28(29)
Qilu University of Technology (CN)
Openalex Percentile: Top 94%
Catalytic C–H Functionalization Methods
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