Research of Characteristics of the Thermal Runaway Process of Full-Size Prefabricated Cabin Energy Storage System

In order to study the characteristics of the thermal runaway process of a full-size prefabricated cabin energy storage system, a full-scale prefabricated cabin energy storage physical fire test platform was designed using 100% SOC energy storage battery packs as the thermal runaway object, and full-scale prefabricated cabin energy storage system physical fire experiments were conducted. This experiment analyzes the early change rules of parameters such as temperature, voltage, CO, and VOC after the energy storage system enters thermal runaway and explores the technical methods to improve the fire protection of electrochemical energy storage systems. The results show that the time when the surface temperature of the runaway cell undergoes a sudden change is 37 s later than the time when the voltage undergoes a sudden change; the CO at the bottom and middle of the runaway cluster reaches the alarm threshold 25 s and 39 s earlier than that at the top of the cluster, respectively, and the peak concentration of CO at the bottom and middle of the cluster is more than three times that at the top of the cluster. The opening of the fan causes the CO concentration on the left side of the thermal runaway cluster to be higher than that of the runaway cluster; before the battery thermal runaway, the VOC concentration at the middle and top of the runaway cluster is generally higher than that at the bottom of the cluster. After thermal runaway occurs, the VOC concentration at the bottom of the thermal runaway cluster exceeds that at other positions of the runaway cluster and the adjacent cluster; the tVOC at the top, middle, and bottom of the thermal runaway cluster is 2296 s, 1681 s, and 1464 s earlier than the tCO, respectively, but the initial detection value of VOC fluctuates more than that of CO.