Approach to the Performance of Polymers Designed Based on Poly(methyl methacrylate) (PMMA)/poly(urethane) (PU) with Recycled Cellulose Nanoparticles from Cold Drink Cups

Transparent high-performance polymers are essential to avoid damage in automotive headlights when exposed to environmental conditions. An approach involving the synthesis of reinforced interpenetrating polymer networks (IPNs) based on poly(methyl methacrylate) (PMMA)/poly(urethane) (PU) with crystalline cellulose (C) is here proposed. The valorization of single-use cups used for cold beverage applications into reinforcement nanoparticle agents is studied through structural and morphological analysis, revealing intermediate crystallinity (52.51%) with a mixture of Iα (52.9%) and Iβ (46.3%) polymorphs in which the initial fiber had no chemical modification after the involved pretreatments. The effect of dispersing 0.1 wt% of C (d = 29 nm and L= 85-200 nm) into 50/50 and 80/20 PMMA/PU ratios is studied as a reinforcement agent under aging and environmental conditions (ASTM D1435-20) for 672 h. PMMA₈₀/PU₂₀ (σ =4 MPa, ε = 54%, E = 7 MPa) led to lower mechanical properties than PMMA₅₀/PU₅₀ (stress σ =14 MPa, strain ε = 94%, E = 83 MPa). PMMA₅₀/PU₅₀/C is reinforced in σ and ε with C addition (σ = 19 MPa, ε = 41%, E = 585 MPa) while PMMA₈₀/PU₂₀/C reduces both (σ = 3 MPa, ε = 51%, E = 5 MPa). This study indicates that aging increases stress while maintaining strain in the first but decreases in the second. The optical properties indicate no severe damage after aging.