Restoring sputter damage by light soaking in silicon carbide-based transparent passivating contact solar cells
<h2>Summary</h2> Crystalline silicon (c-Si) solar cells with hydrogenated nanocrystalline silicon carbide (nc-SiC:H)-based transparent passivating contact (TPC) achieve enhanced short-circuit current density (<i>J</i><sub>SC</sub>) compared to conventional silicon heterojunction (SHJ) solar cells but suffer from lower open-circuit voltage (<i>V</i><sub>OC</sub>). The <i>V</i><sub>OC</sub> loss is largely due to sputter damage during Sn-doped indium tin oxide window layer deposition. We evaluate thermal annealing for damage mitigation but find limited restoration due to differing thermal tolerances of TPC and SHJ contacts. Instead, a direct heat-assisted intensive light-soaking (LiSo) treatment effectively heals the sputter damage, improving <i>V</i><sub>OC</sub> above 735 mV and achieving a certified efficiency of 24.17% ± 0.29%. Detailed investigation highlights the synergistic effects of light and heat in the LiSo process. Additionally, a damage-restoration mechanism related to hydrogen motion is discussed.
Authors
- Kaining Ding (ORCID: https://orcid.org/0000-0003-0329-5951)
- Andreas Lambertz (ORCID: https://orcid.org/0000-0001-8275-6837)
- Muhammad Ainul Yaqin (ORCID: https://orcid.org/0000-0002-0555-9773)
- Uwe Rau (ORCID: https://orcid.org/0000-0003-3526-3081)
- Karsten Bittkau (ORCID: https://orcid.org/0000-0001-5381-2967)
- Alexander Eberst (ORCID: https://orcid.org/0000-0003-2357-7366)
- Binbin Xu (ORCID: https://orcid.org/0000-0001-8184-8852)
- Volker Lauterbach
- Penda Fall
Institutions
- Forschungszentrum Jülich (DE)
- Jülich Aachen Research Alliance (DE)
Publication Details
- Journal
- Cell Reports Physical Science
- Published
- 2025-04-22
- DOI
- https://doi.org/10.1016/j.xcrp.2025.102552
- Citations
- 1
- Primary Topic
- Silicon and Solar Cell Technologies
- Type
- article
- Field-Weighted Citation Impact
- 0.73