Dynamical correlation between ions in liquid seen in real space and time

Controlling ionic transport in liquids is anticipated to provide new scientific and technological opportunities, but it requires accurate knowledge of atomic-scale dynamics of ions beyond the hydrodynamic description. Atomic dynamics in liquids is characterized by strong and dynamical correlations among atoms, which render a conventional approach to describing the dynamics in reciprocal space challenging. We propose an alternative approach to describe liquid dynamics in real space and time using the time-delayed two-body correlation function, Van Hove correlation function, and discuss recent results on the local dynamics in water and electrolytes.

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Publication Details

Journal
Applied Physics Letters
Published
2025-04-21
DOI
https://doi.org/10.1063/5.0256865
Citations
2
Primary Topic
Spectroscopy and Quantum Chemical Studies
Type
article
Field-Weighted Citation Impact
2.49

Funders

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article

Dynamical correlation between ions in liquid seen in real space and time

T. Egami, Yuya Shinohara
2 citations
Applied Physics Letters
Spectroscopy and Quantum Chemical Studies
2.49
article

Dynamical correlation between ions in liquid seen in real space and time

T. Egami, Yuya Shinohara
article en
2 citations

Abstract

Controlling ionic transport in liquids is anticipated to provide new scientific and technological opportunities, but it requires accurate knowledge of atomic-scale dynamics of ions beyond the hydrodynamic description. Atomic dynamics in liquids is characterized by strong and dynamical correlations among atoms, which render a conventional approach to describing the dynamics in reciprocal space challenging. We propose an alternative approach to describe liquid dynamics in real space and time using the time-delayed two-body correlation function, Van Hove correlation function, and discuss recent results on the local dynamics in water and electrolytes.

Applied Physics LettersVol. 126(16)
Oak Ridge National Laboratory (US), Joint Institute for Computational Sciences (US), University of Tennessee at Knoxville (US)
U.S. Department of Energy
Openalex Percentile: Top 12%
Spectroscopy and Quantum Chemical Studies
2.49
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Dynamical correlation between ions in liquid seen in real space and time — T. Egami, Yuya Shinohara · Applied Physics Letters (2025) | TGRS Research Map | TGRS