Asymmetric simple exclusion process with concerted hopping

An important mechanism enabling fast ion diffusion in solid electrolytes is considered to be the significant lowering of the activation barrier when two or more ion particles hop simultaneously between sites, i.e., concerted migration, compared to single-ion hopping. In this study we incorporate a mechanism of simultaneous particle hopping into the asymmetric simple exclusion process, which is an archetypal model for many-particle transportation phenomena, and investigate its impact on particle transport properties. In our model, reflecting ion dynamics, the hopping rates are controlled by the activation energy, inverse temperature, and strength of an external driving field. We first construct an exact solution that describes the steady state of the proposed model. By using this solution, we find that concerted migration substantially increases the particle current and induces a shift of the peak in the fundamental diagram, i.e., the density-current relationship. We also show the presence of a critical temperature that maximizes the current. Additionally, we discuss the implications within parameter regions corresponding to actual materials.

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Publication Details

Journal
Physical Review Research
Published
2025-04-21
DOI
https://doi.org/10.1103/physrevresearch.7.023068
Citations
1
Primary Topic
Stochastic processes and statistical mechanics
Type
article
Field-Weighted Citation Impact
3.69

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article

Asymmetric simple exclusion process with concerted hopping

Yasunobu Ando, K. Kihara, Katsuhiro Nishinari, Takahiro Ezaki
1 citations
Physical Review Research
Stochastic processes and statistical mechanics
3.69
article

Asymmetric simple exclusion process with concerted hopping

Yasunobu Ando, K. Kihara, Katsuhiro Nishinari, Takahiro Ezaki
article en
1 citations

Abstract

An important mechanism enabling fast ion diffusion in solid electrolytes is considered to be the significant lowering of the activation barrier when two or more ion particles hop simultaneously between sites, i.e., concerted migration, compared to single-ion hopping. In this study we incorporate a mechanism of simultaneous particle hopping into the asymmetric simple exclusion process, which is an archetypal model for many-particle transportation phenomena, and investigate its impact on particle transport properties. In our model, reflecting ion dynamics, the hopping rates are controlled by the activation energy, inverse temperature, and strength of an external driving field. We first construct an exact solution that describes the steady state of the proposed model. By using this solution, we find that concerted migration substantially increases the particle current and induces a shift of the peak in the fundamental diagram, i.e., the density-current relationship. We also show the presence of a critical temperature that maximizes the current. Additionally, we discuss the implications within parameter regions corresponding to actual materials.

Physical Review ResearchVol. 7(2)
Shanghai Institute for Science of Science (CN), Institute of Science Tokyo (JP), The University of Tokyo (JP)
Japan Society for the Promotion of Science
Openalex Percentile: Top 11%
Stochastic processes and statistical mechanics
3.69
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