Kinetic and mechanistic studies of cyclohexane oxidation with <i>tert</i>-butyl hydroperoxide over M–N<sub>4</sub> catalysts
Oxidation of cyclohexane with tert -butyl hydroperoxide (TBHP) is a common probe reaction, though the kinetics of this reaction are seldom reported. Here we show that Fe phthalocyanine and Fe-N-C have similar rates and kinetics for this reaction.
Authors
- Ademola Soyemi (ORCID: https://orcid.org/0000-0002-1914-3306)
- Martin G. Bakker (ORCID: https://orcid.org/0000-0003-2584-3947)
- J. W. Harris
- Matthew W. Miller (ORCID: https://orcid.org/0000-0002-7896-7217)
- Tibor Szilvási (ORCID: https://orcid.org/0000-0002-4218-1570)
- Ethan P. Iaia (ORCID: https://orcid.org/0000-0002-1219-328X)
Institutions
- University of Alabama (US)
Publication Details
- Journal
- Reaction Chemistry & Engineering
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5re00031a
- Primary Topic
- Catalysis and Oxidation Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00