Microstructure and Properties of Al-Cr-N Ternary Wear-Resistant Coatings on Cr12MoV Alloy Tool Steel by Multiarc Ion Plating

Al-Cr-N ternary coatings were deposited on the surface of Cr12MoV alloy tool steel via multiarc ion plating technology. The microstructure and mechanical and tribological properties of these coatings were systematically characterized, analyzed, and compared with those of the uncoated substrate specimens. The results indicated that under optimal conditions, Al70Cr30 alloy was effectively ionized, leading to the formation of AlN and CrN phases between Al ions, Cr ions, and nitrogen atoms. These phases were uniformly distributed within the coating, forming an ordered lattice structure. At a bias voltage of −60 V, the deposited Al-Cr-N coating exhibited a uniform and smooth morphology. However, because of the inherent characteristics of arc deposition, droplets and craters were observed on the coating surface as a result of sputtering and back-sputtering effects. The average nanohardness of the Al-Cr-N ternary coating reached 23.8 ± 3.1 GPa, while the coefficient of friction stabilized at approximately 0.7 during the wear process, compared with around 0.8 for the uncoated Cr12MoV substrate. Compared with the uncoated Cr12MoV substrate, the Al-Cr-N coating demonstrated significantly enhanced hardness and wear resistance, thereby effectively improving the performance of Cr12MoV alloy tool steel.