One-Dimensional Electron Gas Confined along Nanowrinkles in a Unidirectional Charge Density Wave Material

Two-dimensional (2D) materials inherently exhibit instabilities. Structurally, this may lead to modulations along the third dimension, e.g., wrinkles. Electronically, 2D instabilities can manifest themselves as charge density waves (CDWs). Although wrinkles can alter anisotropic electronic structures susceptible to forming CDWs, less is known about their impact on broken-symmetry ground states. Here, using scanning tunneling microscopy and spectroscopy, we investigate the CDW states on the wrinkled surface of DyTe<sub>3</sub>. We identify elongated, parallel nanoscale wrinkles stabilized by ribbon-shaped defects. Interestingly, the CDW order persists across the nanowrinkles with a gradual phase shift but is locally suppressed near the defects, where phase windings occur. In addition, these defects induce quantum confinement effects along the nanowrinkles, indicating the presence of one-dimensional metallic states with hole-like dispersion, while angle-resolved photoemission spectroscopy identifies a gap along the wrinkle direction. We ascribe this discrepancy to strain-induced changes in the Fermi surface, which lead to the closure of the gap at the sites of the nanowrinkles. Taken together, our results underscore the complex interplay between structural features and Fermi surface topology, allowing for the deliberate manipulation of quantum states in strongly correlated systems via local crystal deformations.

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Publication Details

Journal
ACS Nano
Published
2025-04-19
DOI
https://doi.org/10.1021/acsnano.4c18943
Citations
2
Primary Topic
Strong Light-Matter Interactions
Type
article
Field-Weighted Citation Impact
2.49

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article

One-Dimensional Electron Gas Confined along Nanowrinkles in a Unidirectional Charge Density Wave Material

Changyoung Kim, Dirk Wulferding, Eunseo Kim, Dong-Hui Lu et al.
2 citations
ACS Nano
Strong Light-Matter Interactions
2.49
article

One-Dimensional Electron Gas Confined along Nanowrinkles in a Unidirectional Charge Density Wave Material

Changyoung Kim, Dirk Wulferding, Eunseo Kim, Dong-Hui Lu, S.-I. Lee, Doo‐Hee Cho, Makoto Hashimoto, Sunghun Kim, Jongho Park, Hyungryul Yang
article en
2 citations

Abstract

Two-dimensional (2D) materials inherently exhibit instabilities. Structurally, this may lead to modulations along the third dimension, e.g., wrinkles. Electronically, 2D instabilities can manifest themselves as charge density waves (CDWs). Although wrinkles can alter anisotropic electronic structures susceptible to forming CDWs, less is known about their impact on broken-symmetry ground states. Here, using scanning tunneling microscopy and spectroscopy, we investigate the CDW states on the wrinkled surface of DyTe<sub>3</sub>. We identify elongated, parallel nanoscale wrinkles stabilized by ribbon-shaped defects. Interestingly, the CDW order persists across the nanowrinkles with a gradual phase shift but is locally suppressed near the defects, where phase windings occur. In addition, these defects induce quantum confinement effects along the nanowrinkles, indicating the presence of one-dimensional metallic states with hole-like dispersion, while angle-resolved photoemission spectroscopy identifies a gap along the wrinkle direction. We ascribe this discrepancy to strain-induced changes in the Fermi surface, which lead to the closure of the gap at the sites of the nanowrinkles. Taken together, our results underscore the complex interplay between structural features and Fermi surface topology, allowing for the deliberate manipulation of quantum states in strongly correlated systems via local crystal deformations.

ACS NanoVol. 19(16)
Seoul National University (KR), Yonsei University (KR), SLAC National Accelerator Laboratory (US), Sejong University (KR), Stanford Synchrotron Radiation Lightsource (US), Ajou University (KR)
National Research Foundation of Korea, Institute for Basic Science
Affordable and clean energy
Openalex Percentile: Top 12%
Strong Light-Matter Interactions
2.49
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