Visible-Light-Accelerated Decarboxylative <i>N-</i>Allylation of γ-Methylidene-δ-valerolactones via Synergistic Pd(0)/Cu(II)/Riboflavin Catalysis
We report a visible-light-accelerated decarboxylative <i>N</i>-allylation of methylidene-δ-valerolactones via synergistic Pd(0)/Cu(II)/riboflavin catalysis. This method enables efficient coupling of diverse anilines and lactones under mild conditions, achieving an up to 93% yield.
Authors
- Daoshan Yang (ORCID: https://orcid.org/0000-0002-3047-5416)
- K. Sandy Pang (ORCID: https://orcid.org/0000-0002-0683-2129)
- Beichen Xue (ORCID: https://orcid.org/0000-0001-9862-269X)
- Ran Song
- Xin Li (ORCID: https://orcid.org/0000-0001-9050-6504)
- Wen Si (ORCID: https://orcid.org/0000-0002-9850-0702)
- Jian Lv (ORCID: https://orcid.org/0000-0001-7641-5411)
- Haobing Yang
Institutions
- Qingdao University of Science and Technology (CN)
- Nanjing Forestry University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-04-18
- DOI
- https://doi.org/10.1021/acs.orglett.5c01107
- Citations
- 2
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- Natural Science Foundation of Shandong Province
- Qingdao University of Science and Technology