Synergistic regulation of the Co microenvironment in MOF-74 for olefin epoxidation <i>via</i> lanthanum modification and defect engineering
Lanthanum modification and defect engineering were used to regulate the microenvironment of Co in MOF-74. DFT demonstrated the strong hybridization between the unpaired electrons of Co and O and explained the enhanced O 2 activation for epoxidation.
Authors
- Hongyi Gao (ORCID: https://orcid.org/0000-0001-9312-5504)
- Tao Ban (ORCID: https://orcid.org/0000-0001-7532-1667)
- Xingtian Shu
- Yibin Luo (ORCID: https://orcid.org/0000-0002-8286-857X)
- Zuoshuai Xi (ORCID: https://orcid.org/0009-0005-9643-662X)
- Zhiyuan Liu (ORCID: https://orcid.org/0000-0002-4943-6572)
- Ge Wang (ORCID: https://orcid.org/0000-0002-4069-4284)
- Chang‐An Wang (ORCID: https://orcid.org/0000-0002-5731-2748)
Institutions
- Sinopec (China) (CN)
- Sinopec Research Institute of Petroleum Processing
- University of Science and Technology Beijing (CN)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta01712b
- Citations
- 7
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 3.76
Funders
- National Natural Science Foundation of China
- Beijing Municipal Natural Science Foundation